Greener, more efficient process developed to produce hydrogen from natural gas

Hydrogen is certainly one of the big candidates when it comes to finding cleaner fuels to replace petroleum. While it only produces water when burnt as fuel, the process of obtaining hydrogen from natural gas is not quite so eco-friendly – it consumes a lot of energy, and creates carbon dioxide. Now a new process being developed at the Netherlands’ Eindhoven University of Technology (TU/e) promises a much more efficient, innocuous alternative.

Traditionally, a process known as “steam reforming” is used to produce hydrogen from natural gas. It requires pressures as high as 25 bar (363 psi) and temperatures up to 850 C (1562 F), while also incorporating multistage subsequent separation and purification units. In the post-processing phase, large amounts of CO2 either must be dealt with, or are released into the atmosphere.

TU/e’s Dr. Mohamed Halabi has created a system called “sorption enhanced catalytic reforming of methane,” which uses unique catalyst/sorbent materials instead of steam reforming. The process takes place in a packed bed reactor, with hydrogen being produced on the Rhodium-based catalyst, and the cogenerated CO2 then being absorbed by the Hydrotalcite-based sorbent. This keeps the carbon from escaping into the environment, and results in “high-purity” hydrogen with carbon impurities of less than 100 parts-per-million.

The system’s fuel conversion efficiency has been measured at 99.5 percent.

Energy requirements for the technology are relatively low, as temperatures need only be between 400 and 500 C (752-932 F), with a pressure of 4.5 bar (65 psi). Additionally, reactors utilizing the process could be much smaller than those presently in use, to the point that Halabi is envisioning systems that could be used in businesses or homes.

Powder Metallurgy / Introduction / Process / Methods

Definition:

The Process of producing components from metallic powder parts made by powder metallurgy may contain non-metallic constituents to improve the bonding qualities and properties.

Number and variety of products made by powder metallurgy are continuously increasing:

1. Tungsten Filaments for Lamps
2. Contact Point relays
3. Self lubricating bearings
4. Cemented carbides for cutting tools etc.

 

Characters of Metal Powders:

• Shape:

It is influenced by the way it’s made. The shape may be spherical (atomization) (Electrolysis) flat or angular (Mechanical crushing). The particle shape influences the flow characteristics of powders.

• Particle Size (Fineness) and size distribution:

Particle Size and Distribution are important factors which controls the porosity, Compressibility and amount of shrinkage. Proper particle size and size distribution are determined by passing the powder through a standard sieves ranging from 45 to 150 micrometer mesh.

• Flowability:

The ability of the powders to flow readily and conform to the mould cavity. The flow rate helps to determine to possible production rate.

• Compressibility:

It’s defines as the volume of initial powder (Powder loosely filled in cavity) to the volume of compact part. Depends on particle shape & size distribution.

• Apparent Density:

The Apparent density depends on particle size is defined as the ratio of volume to weight of loosely filled mixture.

• Green strength:

It refer to strength of a compact part prior to sintering. It depends on compressibility and helps to handle the parts during the mass production.

• Purity:

Impurities affects sintering & Compacting Oxides & Gaseous impurities can be removed from the part during sintering by the use of a reducing atmosphere.

• Sintering ability:

It is the ability which promotes bonding of particles by the application of heat.

 

Powder Metallurgy Process steps:

 

 

 

 

Manufacture of Metal Powders:

Methods:

• Mechanical pulverization:

Machining, Drilling or Grinding of metals is used to convert them to powders.

• Machining:

It Produces coarse particles (Flack form) especially Magnesium powders.

• Milling or Grinding:

It suitable for brittle materials.

• Shorting:

The process of dropping molten metal through a Sieve or small orifice in to water. This produces Spherical particles or larger size. Commonly used for metals of low melting point.

 

• Atomizing:

In this molten metal is forced through a nozzle, and a stream of compressed air, stream or Inert gas is directed on it break up into five particles. Powders obtained in irregular in shapes. Atomization commonly used for aluminium, Zinc, Tin, Cadmium and other metals of low melting point.

 

• Electrolytic deposition:

It’s used mainly for producing iron and copper powders. These are dense structure with low apparent density. It consists of depositing metal on cathode plate by conventional electrolysis processes. The Cathode paltes are removed and the deposited powder is scraped off. The powder is wasted, dried, screened & oversized particles are milled or ground for fineness. The powder is further subjected to heat treatment to remove the work hardening effect.

• Chemical reduction:

It’s used for producing iron, Copper, Tungsten, Molybdenum, Nickel & Cobalt powder process consists of reducing the metal oxides by means of carbon monoxide or Hydrogen. After reduction, the powder is usually ground & Sized.

 

Forming to shape:

1. The process of mixing the powders is called Blending.
2. The Loose powders are formed in to shape by compacting.

METALLURGY

Definition:

The Process of producing components from metallic powder parts made by powder metallurgy may contain non-metallic constituents to improve the bonding qualities and properties.

Number and variety of products made by powder metallurgy are continuously increasing:

1. Tungsten Filaments for Lamps
2. Contact Point relays
3. Self lubricating bearings
4. Cemented carbides for cutting tools etc.

 

Characters of Metal Powders:

• Shape:

It is influenced by the way it’s made. The shape may be spherical (atomization) (Electrolysis) flat or angular (Mechanical crushing). The particle shape influences the flow characteristics of powders.

• Particle Size (Fineness) and size distribution:

Particle Size and Distribution are important factors which controls the porosity, Compressibility and amount of shrinkage. Proper particle size and size distribution are determined by passing the powder through a standard sieves ranging from 45 to 150 micrometer mesh.

• Flowability:

The ability of the powders to flow readily and conform to the mould cavity. The flow rate helps to determine to possible production rate.

• Compressibility:

It’s defines as the volume of initial powder (Powder loosely filled in cavity) to the volume of compact part. Depends on particle shape & size distribution.

• Apparent Density:

The Apparent density depends on particle size is defined as the ratio of volume to weight of loosely filled mixture.

• Green strength:

It refer to strength of a compact part prior to sintering. It depends on compressibility and helps to handle the parts during the mass production.

• Purity:

Impurities affects sintering & Compacting Oxides & Gaseous impurities can be removed from the part during sintering by the use of a reducing atmosphere.

• Sintering ability:

It is the ability which promotes bonding of particles by the application of heat.

 

Powder Metallurgy Process steps:

 

 

 

 

Manufacture of Metal Powders:

Methods:

• Mechanical pulverization:

Machining, Drilling or Grinding of metals is used to convert them to powders.

• Machining:

It Produces coarse particles (Flack form) especially Magnesium powders.

• Milling or Grinding:

It suitable for brittle materials.

• Shorting:

The process of dropping molten metal through a Sieve or small orifice in to water. This produces Spherical particles or larger size. Commonly used for metals of low melting point.

 

• Atomizing:

In this molten metal is forced through a nozzle, and a stream of compressed air, stream or Inert gas is directed on it break up into five particles. Powders obtained in irregular in shapes. Atomization commonly used for aluminium, Zinc, Tin, Cadmium and other metals of low melting point.

 

• Electrolytic deposition:

It’s used mainly for producing iron and copper powders. These are dense structure with low apparent density. It consists of depositing metal on cathode plate by conventional electrolysis processes. The Cathode paltes are removed and the deposited powder is scraped off. The powder is wasted, dried, screened & oversized particles are milled or ground for fineness. The powder is further subjected to heat treatment to remove the work hardening effect.

• Chemical reduction:

It’s used for producing iron, Copper, Tungsten, Molybdenum, Nickel & Cobalt powder process consists of reducing the metal oxides by means of carbon monoxide or Hydrogen. After reduction, the powder is usually ground & Sized.

 

Forming to shape:

1. The process of mixing the powders is called Blending.
2. The Loose powders are formed in to shape by compacting.

METALLURGY

Definition:

The Process of producing components from metallic powder parts made by powder metallurgy may contain non-metallic constituents to improve the bonding qualities and properties.

Number and variety of products made by powder metallurgy are continuously increasing:

1. Tungsten Filaments for Lamps
2. Contact Point relays
3. Self lubricating bearings
4. Cemented carbides for cutting tools etc.

 

Characters of Metal Powders:

• Shape:

It is influenced by the way it’s made. The shape may be spherical (atomization) (Electrolysis) flat or angular (Mechanical crushing). The particle shape influences the flow characteristics of powders.

• Particle Size (Fineness) and size distribution:

Particle Size and Distribution are important factors which controls the porosity, Compressibility and amount of shrinkage. Proper particle size and size distribution are determined by passing the powder through a standard sieves ranging from 45 to 150 micrometer mesh.

• Flowability:

The ability of the powders to flow readily and conform to the mould cavity. The flow rate helps to determine to possible production rate.

• Compressibility:

It’s defines as the volume of initial powder (Powder loosely filled in cavity) to the volume of compact part. Depends on particle shape & size distribution.

• Apparent Density:

The Apparent density depends on particle size is defined as the ratio of volume to weight of loosely filled mixture.

• Green strength:

It refer to strength of a compact part prior to sintering. It depends on compressibility and helps to handle the parts during the mass production.

• Purity:

Impurities affects sintering & Compacting Oxides & Gaseous impurities can be removed from the part during sintering by the use of a reducing atmosphere.

• Sintering ability:

It is the ability which promotes bonding of particles by the application of heat.

 

Powder Metallurgy Process steps:

 

 

 

 

Manufacture of Metal Powders:

Methods:

• Mechanical pulverization:

Machining, Drilling or Grinding of metals is used to convert them to powders.

• Machining:

It Produces coarse particles (Flack form) especially Magnesium powders.

• Milling or Grinding:

It suitable for brittle materials.

• Shorting:

The process of dropping molten metal through a Sieve or small orifice in to water. This produces Spherical particles or larger size. Commonly used for metals of low melting point.

 

• Atomizing:

In this molten metal is forced through a nozzle, and a stream of compressed air, stream or Inert gas is directed on it break up into five particles. Powders obtained in irregular in shapes. Atomization commonly used for aluminium, Zinc, Tin, Cadmium and other metals of low melting point.

 

• Electrolytic deposition:

It’s used mainly for producing iron and copper powders. These are dense structure with low apparent density. It consists of depositing metal on cathode plate by conventional electrolysis processes. The Cathode paltes are removed and the deposited powder is scraped off. The powder is wasted, dried, screened & oversized particles are milled or ground for fineness. The powder is further subjected to heat treatment to remove the work hardening effect.

• Chemical reduction:

It’s used for producing iron, Copper, Tungsten, Molybdenum, Nickel & Cobalt powder process consists of reducing the metal oxides by means of carbon monoxide or Hydrogen. After reduction, the powder is usually ground & Sized.

 

Forming to shape:

1. The process of mixing the powders is called Blending.
2. The Loose powders are formed in to shape by compacting.