Artificial Leaf Solar Power

Photosynthesis:

Photosynthesis is the process by which plants, some bacteria, and some protists use the energy from sunlight to produce sugar, which cellular respiration converts into ATP, the “fuel” used by all living things. The conversion of unusable sunlight energy into usable chemical energy, is associated with the actions of the green pigment chlorophyll.

They release molecular oxygen and remove CO₂ (Carbon Dioxide) from the air.

ATP: Adenosine Tri-Phosphate (ATP)  Here the energy is stored in living systems; it consists of a Nucleotide (with Ribose sugar) with Three Phosphate groups.

Why is photosynthesis important:

Nearly all living things depend on the energy produced from photosynthesis for their nourishment. Animals need the plants for food as well as oxygen. Only green plants are able to change light energy into chemical energy stored in food, thus they are vital to life on Earth.

Solar cells:

Conventional solar cells are also called as Photo Voltaic Cells. These cells are made out of semiconducting material, usually silicon. When light hits the cells, they absorb energy though photons. This absorbed energy knocks out electrons in the silicon, allowing them to flow. By adding different impurities to the silicon such as phosphorus or boron, an electric field can be established. This electric field acts as a diode, because it only allows electrons to flow in one direction. Consequently, the end result is a current of electrons, better known to us as electricity.

Drawbacks of Solar cells:

They can only achieve efficiencies around 10% and they are expensive to manufacture. The first drawback, inefficiency, is almost unavoidable with silicon cells. This is because the incoming photons, or light, must have the right energy, called the band gap energy, to knock out an electron. If the photon has less energy than the band gap energy then it will pass through. If it has more energy than the band gap, then that extra energy will be wasted as heat.

Artificial Leaf:

Mixing of Photosynthesis + Conventional Solar Cells + Hydrogen Fuel Cell

This Leaf device combines a commercially available solar cell (Silicon) with a pair of inexpensive catalysts made of Cobalt and Nickel that split water into Oxygen and Hydrogen. The hydrogen can be stored and used as an energy source. (For example to power a fuel cell).

The collection and storage of the sun’s energy as hydrogen fuel is a key step in overcoming one of the limitations of solar power — it generates energy when the sun is shining, but it needs to be stored somewhere to be useful at night and in cloudy weather. Batteries are one place to store the energy, but it is limited. Storing solar energy as hydrogen fuel could be an answer for producing the electricity continuously.

Using this approach, a solar panel roughly one square meter bathed in water could produce enough hydrogen to supply electricity for a house.

INFRARED CURVING

The coatings and paint industries strive to provide high technology coatings while reducing volatile organic compounds and energy consumption to produce a finished coating. Conventionally Convection ovens are used to cure the coatings. But this process which uses electric heaters is not an optimal process and is associated with various disadvantages.

Improved technologies are available today, which can either replace or improve the convection curing process. Infrared Curing is such a technology which uses Infrared rays emitted by an Infrared emitter to provide the required cure. Infrared curing applies light energy to the part surface by direct transmission from an emitter. Some of the energy emitted will be reflected off the surface, some is absorbed into the polymer and some is transmitted into the substrate.

This direct transfer of energy creates an immediate reaction in the polymer and cross linking begins quickly once the surface is exposed to the emitter. Infrared emitters are often custom manufactured to suit the production demand. The various aspects of Infrared curing and convection curing and the possibility of combining these two technologies into a singe system will be discussed in this seminar.

How it Works

Infrared heating is a direct form of heating. The source of the heat (the infrared emitter or lamp) radiates: energy that is absorbed by the product directly from the emitter. That is, the heat energy is not transferred through an intermediate medium. This is one reason for  the  inherent high-energy efficiency of infrared systems. For  example, hot air heating  first needs to heat air; the air then heats the product by convection.

Infrared  energy is directed  to  the  product. When  the  product absorbs this energy, it is then converted into heat. Infrared energy is dispersed from the source in much the same  way as visible light. Exposed product surfaces easily absorb  the  infrared  energy and  become  heated. Therefore, heating effectiveness is related to line-of-sight between the source and the product. Depending on the coating and/or product substrate material, this heat is further thermally conducted.

The ability of the product to absorb energy is also known as its “emissivity”. A theoretical body that absorbs all energy is termed a “black body”. A black body has an emissivity of 1. A highly reflective body would have a low emissivity value, approaching 0. (Reflectivity is the inverse of emissivity).

The potential of a product to become heated with infrared is related to the following:
• Watt density (total output power) of the source
• Wavelength (temperature) of the source
• Distance from the source to the product
• Reflective characteristics of the oven cavity
• Air movement and temperature in the oven
• Time product is exposed to the source
• Ratio of exposed surface area to the mass of the product
• Specific heat of the product
• Emissivity of the product
• Thermal conductivity of the product

CURING

Curing is a process of baking surface coatings so as to dry them up quickly. Curing is a broad term which means all the techniques employed for the finishing operations incurred during part production. Curing essentially involves either the melting of the coating or evaporation of volatile fluids present in the coating by the application of heat energy.

Curing is given to a wide range of materials both organic and inorganic. Usually curing is given to materials like ,

” Paints
” Enamel
” Liquor
” Powder coatings
” Varnishes
” Epoxy coatings
” Acrylic coatings
” Primers Etc.

Curing is also given to Rubber and Latex .The principle used for curing can also be used for drying rice and grains.

CONVECTION CURING

Convection ovens are usually used for curing purposes. Traditional convection ovens use heated forced air to provide the necessary cure. Convection ovens consist of a chamber lined on the inside with Electric heaters. The shape of the chamber will be in accordance to the shape or geometry of the part being cured. A series of blowers circulate the heated air around providing the required cure. This process depends on convection to transfer heat from hot air to body surface and conduction to transfer heat to the interior of the surface. The air being delivered is held at temperature using closed-loop control, which provides predictable, repeatable results. Typically a temperature of around 250-500 degree Fahrenheit is required for paint or powder. Though convection ovens are widely used today they have certain disadvantages, which chokes the overall productivity of a company
Disadvantages of convection ovens :

” Fairly long heating times:-

Convection is a slow process. It takes a considerable amount of time for the heaters to heat up and raise the temperature of air to the required level. This causes a lag in the process and hence the curing time increases. Longer curing time spells reduced assembly line movement. This in turn reduces productivity.

” High energy consumption:-

A convection column dryer uses around 2000 BTU(British Thermal Unit) of energy to remove 1 pound of moisture. They use around 7.7 KW of electrical energy to dry a ton of rice. These are significantly larger figures for any company trying to bring energy consumption under control. The additional use of blowers and compressors further increases energy consumption.

” Large floor area required:-

Convection ovens are bulky in nature. Due to the presence of compressors and blowers, additional space is needed, which in turn increases the floor area requirement.

” Air circulation is required:-

Convection heating requires a medium for transmission of heat. Hence blowers are employed for good circulation of heated air. This increases the overall cost of the equipment.